Self-catalytic behavior of carbon nanotubes.

نویسندگان

  • Zhenping Zhu
  • Yi Lu
  • Dahong Qiao
  • Shuli Bai
  • Tuoping Hu
  • Li Li
  • Jianfeng Zheng
چکیده

Self-catalytic behavior of multi-walled carbon nanotubes is proposed and validated experimentally under the conditions in which metal catalysis was previously figured to work only. The self-catalysis could support the nanotube nucleation and radial and axial developing processes. This result should lead to a new and better understanding of the growth mechanism of carbon nanotubes in a metal catalytic process.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Hydrodynamic Studies of Fluidized Bed Chemical Vapor Deposition Reactors to Produce Carbon Nano Tubes via Catalytic Decomposition over Co/Pd MgO

The hydrodynamic studies of fluidized bed reactor has been reported in terms of pressure drop, minimum fluidization velocity and bed volume expansion to contribute to the optimization of the CNTs production parameters in fluidized bed reactors. Minimum fluidization velocity and pressure drop, as the most important parameters, were taken into account for the investigation of the hydrodynamic beh...

متن کامل

Effects of Confinement in Carbon Nanotubes on the Performance and Lifetime of Fischer-Tropsch Iron Nano Catalysts

The effects of confinement in carbon nanotubes on Fischer-Tropsch (FT) activity, selectivity and lifetime of Carbon NanoTubes (CNTs) supported iron catalysts are reported. A method was developed to control the position of the catalytic sites on either inner or outer surface of carbon nanotubes. TEM analyses revealed that more than 80% of iron oxide particles can be controlled to be position...

متن کامل

The Effect of Simultaneous Incorporation of PTFE Nanoparticles and Carbon Nanotubes on the Tribological Behavior of Ni-P Coating

In some engineering fields, wear resistance and a low friction coefficient are required at the sametime. In this research, PTFE nanoparticles and carbon nanotubes were co-deposited within Ni-Pmatrix to obtain an Ni-P-PTFE-CNT hybrid coating for wear resistance and a low friction coefficient.The tribological properties of the deposits were evaluated by pin on disc tribometer. T...

متن کامل

Multi-walled carbon nanotubes supported palladium nanoparticles: Synthesis, characterization and catalytic activity towards methanol electro oxidation in alkaline media

Palladium nanoparticles supported on multi-walled carbon nanotubes (Pd/MWCNTs) have been synthesized using a modified polyol reduction method and its performance in methanol oxidation reactions has evaluated. The morphology of palladium on MWCNTs was characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The catalytic performance of synthesized catalyst ...

متن کامل

Voltammmetric Determination of Captopril Using Multiwall Carbon Nanotubes Paste Electrode in the Presence of Isoproterenol as a Mediator

The electrocatalytic oxidation of captopril (CAP) was studied by modified carbon nanotubes paste electrode in the presence of isoproterenol (ISPT) using cyclic voltammetry (CV), chronoamperometry and square wave voltammetry (SWV). Also, the values of catalytic rate constant (k), and electron transfer coefficient (α) for CAP were calculated. The mechanism of CA electrochemical behavior at the mo...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 127 45  شماره 

صفحات  -

تاریخ انتشار 2005